Spectroscopy of Σ 0 0 → Π 1 0 Vibrational - Tunneling - Rotational Band in
نویسندگان
چکیده
A number of vibrational-tunneling-rotational (VTR) transitions in the range of 195-298 GHz belonging to theΣ00 → Π10 hindered rotation band in Rg·ND3 (Rg = Ne, Kr) complexes are observed in absorption in a free supersonic jet, using the pulsed fast scan submillimeter wave spectroscopic technique (FASSST). The data obtained in this experiment, combined with previously obtained data on the Ar·ND3 complex, were used to construct a qualitative model describing the inversion-tunneling motion in the lowest states of the Rg·ND3 complexes.
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تاریخ انتشار 2002